The Account discovery feature is located in Administration– Privileged account management – Providers in Devolutions Cloud and discovers accounts of a provider's environment.
From the scan results of an account discovery configuration, PAM operators can view the group assignments of a discovered account and manage them directly.

To open the group assignment form, select a discovered account in the scan results. The form displays the account details and a list of its assigned groups, each with an associated risk score and a checkbox for selection.
In the scan results, select a discovered account.
In the group assignment form, select one or more groups using the checkboxes.
Click Add to JIT.
A confirmation message appears listing each group with a status of Added or Duplicate.
In the scan results, select a discovered account.
In the group assignment form, select one or more groups using the checkboxes.
Click Remove assignment.
In the confirmation prompt, click Remove to confirm.
A confirmation message lists all groups the account was successfully removed from.
The Remove assignment button is only enabled when at least one group is selected.